10 Coffee Bean Processing Decaffeination The term decaffeinated coffee may strike some as an oxymoron, but a number of coffee drinkers relish the taste of coffee but cannot tolerate the jolt from caffeine. The main methods of decaffeination are based on chemical solvents, carbon filtering, carbon dioxide extraction, or triglycerides. In all cases, to make “decaf,” the caffeine is removed in the green bean stage, before the coffee is roasted. The process of decaffeination was initially solvent-based (in the early 20th century using benzene but later using methylene chloride or ethyl acetate). In the direct method, the coffee beans are steamed and then rinsed by the chemical agent. In the indirect method, the chemical agent never touches the beans but treats the water-base coffee solution in which the beans are first soaked. Although some high-volume companies still decaffeinate by using solvents (mainly et...